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Material Selection · Chemical

Acids. Bases.
Solvents. Salts.
Chemical-proof.

Material selection for specific chemical environments. Different chemicals attack different materials. Verify compatibility before specifying.

01 · Key principles

Key principles.

Sulfuric acid (concentrated)

Lead, tantalum

Concentrated H₂SO₄: lead historical, tantalum modern.

Sulfuric acid (dilute)

316L, Hastelloy

Dilute H₂SO₄ less aggressive. 316L often acceptable.

Hydrochloric acid

Hastelloy, tantalum, PTFE

HCl very aggressive. Specialty alloys or PTFE.

Hydrofluoric acid

Monel, lead, PTFE

HF dissolves stainless. Monel preferred metal.

Sodium hydroxide

Nickel, Inconel

NaOH attacks aluminum, stainless. Nickel preferred.

Chlorine

Titanium, hastelloy

Chlorine atmosphere: titanium and hastelloy options.

Solvents (organic)

316L, PEEK

Most organic solvents OK with 316L. PEEK for aggressive.

Saltwater

316L, duplex, Monel

Marine standard. Choose per severity.

Mineral oils

Carbon steel

Most petroleum products non-corrosive to steel.

FAQ

How to check chemical compatibility?

Manufacturer compatibility charts. ASM Materials Chemical Compatibility Database. Test coupons for unknown.

PTFE vs PEEK chemical resistance?

PTFE: virtually all chemicals at moderate temperature. PEEK: most chemicals at high temperature, weaker against some solvents.

Crevice/pitting corrosion in chemicals?

Localized corrosion in stagnant or trapped chemical exposure. Avoid crevices. Use higher-PRE alloys.

Galvanic effects in chemical environments?

Multiple metals + electrolyte chemical = galvanic corrosion. Use single metal or insulate.

Temperature affects chemical attack?

Major effect. Many materials OK at room temperature fail at elevated. Verify per service temperature.

Specifying chemical-resistant material?

Specify chemical, concentration, temperature, exposure duration. We can recommend per environment.

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