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Kovar · ASTM F15 · FeNiCo

Glass-to-metal seals.
5 ppm/°C CTE.
Hermetic packaging.

Kovar (29% nickel, 17% cobalt, iron balance) has thermal expansion that precisely matches borosilicate glass — enabling crack-free glass-to-metal seals for vacuum tubes, hermetic electronic packaging, sensor feedthroughs. Century of electronics industry use.

01 · Grades & variants

Kovar and related alloys.

Kovar is one of a family of glass-sealing alloys with CTE matched to specific glasses — alumina ceramics, borosilicate glass, hard glass.

Kovar (ASTM F15)

Borosilicate glass

Standard Kovar — 29% Ni, 17% Co, 54% Fe. CTE matches borosilicate glass (Pyrex). Electronics industry workhorse.

Invar 42

Pyrex · ceramic

42% Ni iron alloy. CTE 4.5 ppm/°C — matches soft Pyrex and some ceramics. Used for semiconductor lead frames.

Alloy 52

Soft glass · Pt sub

52% Ni iron. CTE matches platinum — used as substitute for platinum in glass sealing. Specialty.

Alloy 46

Hard glass

46% Ni iron. Higher CTE for hard-glass applications. Used for specialty vacuum tubes.

Alloy 39

Ceramic sealing

39% Ni with cobalt. CTE matches alumina ceramic for hermetic ceramic-to-metal seals.

Kovar Plated

Ni · Au plated

Kovar with nickel or gold plating for solderability, corrosion resistance. Standard form for semiconductor packaging.

02 · Why this material

Why Kovar dominates hermetic packaging.

Any substitute must match Kovar's exact CTE curve — matching it in single points is easy, matching across wide temperature range is difficult.

CTE-matched to glass

5.0 ppm/°C essentially identical to borosilicate glass from room temperature to 450 °C. No thermal stress in glass-metal seals.

Hermetic seal

Glass-Kovar seal is vacuum-tight and helium-leak-tight. Critical for vacuum tubes, MEMS packaging, hermetic electronics.

Welldable and braceable

Standard welding and brazing to make complete hermetic packages. Can be plated for gold-wire bond compatibility.

Century of process development

Since 1930s. Established manufacturing processes, alloy consistency, supply chain. Low technical risk.

03 · Applications

Kovar applications.

Hermetic electronic packaging

Military and aerospace hermetic IC packaging — Kovar lid, glass seal around leads

Vacuum tube feedthroughs

Electrical feedthroughs for vacuum tubes, electron guns, ion sources

Laser diode packages

Hermetic laser diode packages — protect sensitive diodes from moisture

MEMS packaging

MEMS device hermetic packages — sensor protection

Pressure sensors

Hermetic pressure sensor packages — maintain reference vacuum

Optoelectronic packages

Fiber optic transceiver packages, photonic integrated circuits

Reed switches

Hermetic reed switch assemblies sealed in glass

Rubidium clocks

Atomic clock rubidium cell packaging

Satellite electronics

Space-grade hermetic packaging for satellite electronics

04 · Finishing

Kovar finishing.

As-machined

Silver metallic. Ra 1.6 µm typical. Similar appearance to nickel-iron alloys.

Nickel plated

Standard underlayer for gold plating. Prevents iron diffusion to surface.

Gold plated

Standard for wire-bonding, corrosion, solderability. 0.5-2.5 µm thick typical.

Oxidized

Controlled surface oxidation before glass sealing — aids glass bonding.

Brazed

Standard for assembly. Gold-nickel or copper-silver brazing preferred.

Weldable

Laser, TIG, or electron beam welding all standard on Kovar.

Cleaned

Ultrasonic cleaning to semiconductor-grade cleanliness for critical packaging.

Glass sealed

Primary purpose — sealed into borosilicate glass in specialized facilities.

FAQ

Kovar questions.

Borosilicate glass has CTE of 5 ppm/°C. Kovar has matched 5 ppm/°C CTE. When heated together to ~900 °C (glass softens), they bond chemically. On cooling, both contract at the same rate — no residual stress at the interface. Result: hermetic seal that doesn't crack with thermal cycling. If mismatched CTE were used, thermal contraction differential would create stress and crack the glass.
Kovar is necessary specifically for glass-to-metal seals. For non-sealed applications (general electronic enclosures, structural parts), stainless steel is cheaper and better. Don't specify Kovar unless you're making a glass-metal seal, ceramic-metal seal, or CTE-matched electronic package. Kovar is a specialty alloy for specialty applications.
Kovar work-hardens (like stainless), low thermal conductivity (heat concentrates at tool), magnetic (can cause chip adherence issues). Solutions: sharp carbide tooling, slow cutting speeds (50-80 m/min), flood coolant, demagnetize workpiece if issues arise. Tolerance ±0.025 mm achievable. Our semiconductor packaging customers routinely order precision Kovar parts with success.
Kovar raw material: $30-60/kg. About 5-10× mild steel but similar to nickel alloys. Available in standard bar, plate, and sheet sizes. 3-4 week lead time typical for non-stocked sizes. For semiconductor and hermetic packaging orders, Kovar is standard and readily available.
Kovar has moderate corrosion resistance — better than mild steel, worse than stainless. For electronics applications (typically enclosed, controlled environments), corrosion isn't usually critical. For parts exposed to humidity or chemistry, specify nickel or gold plating. Never use bare Kovar in corrosive service — it will rust.
Kovar for borosilicate glass. Alloy 52 for soft glass. Alloy 46 for hard glass. Alloy 39 for alumina ceramic. Platinum and palladium for specialty precision seals (expensive). For polymer-to-metal seals, standard metals work — CTE matching only matters for glass and ceramic sealing. For semiconductor chip attach, matched-CTE alloys ensure long-term reliability over thermal cycling.
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